Product ID:PERMA-LOK LM 113
MSDS Date:10/24/1990
FSC:8040
NIIN:00N021995
MSDS Number: BLTMX

NATIONAL STARCH & CHEMICAL CO

FINDERNE AVENUE
BRIDGEWATER, NJ 08807
US

Emergency Phone: 908-685-5000

Info Phone: 908-685-5000

Preparer: PHILIP A TOSCANO

Cage: 85091

NATIONAL STARCH AND CHEMICAL CORP

6500 BRIDGEWATER, NJ 08807 US

Telephone: 908685-5306

Cage: 85091

DRINKING, SMOKING, OR USING TOILET

RTECS: 9999999ZZ

METHACRYLIC ACID, DIESTER WITH TETRAETHYLENE GLYCOL;

CAS: 109-17-1

Fraction By Weight: >1%

METHACRYLIC ACID, 2-HYDROXYETHYL ESTER; (HYDROXYETHYL

CAS: 868-77-9

Fraction By Weight: >1%

HYDROPEROXIDE, ALPHA, ALPHA-DIMETHYLBENZYL-; (CUMENE

CAS: 80-15-9

RTECS: MX2450000

Fraction By Weight: >1%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,2-BENZISOTHIAZOLIN-3-ONE,1,1-DIOXIDE; (SACCHARIN)

CAS: 81-07-2

RTECS: DE4200000

Fraction By Weight: 2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

HEAT & PRESSURE. VENT DISPOSAL CONTR TO PVNT

RTECS: 9999999ZZ

SURFACE CONDITIONER & DISPOSE OF AS SOLID WASTE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS 2 & 3
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: IRRIT. MAY INJURE EYE TISS
IF NOT REMOVED PROMPTLY. SKIN: FREQUENT/PRLNG CONT MAY IRRIT/CAUSE
DERMAT. MAY CAUSE SENSIT, A PARTIAL/WHOLE-BODY DERMATITIC RASH
EXPERIENCED AFTER EXPOS, HOWEVE R MINIMAL. INHAL: BASED ON ITS LOW
VOLAT, PROD IS NOT CONSIDERED TO BE A RESP HAZ UNDER NORMAL CNDTNS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SACCHARIN: GROUP 2B (IARC), GROUP 2
(NTP).
Effects of Overexposure:HLTH HAZ: OF USE. IRRIT &/OR TOX VAPS MAY BE
RELSD AT ELEVATED TEMPS. INGEST: EFTS HAVE NOT BEEN EVALUATED BUT
ARE ASSUMED TO CAUSE NAUS/VOMIT. CHRONIC: IN CERTAIN INDIVIDUALS,
SENSIT MAY OCCUR CAUSIN G DERMAT W/EVEN MINIMAL CONT. DUE TO SKIN
ABSORPTION W/ EXCESSIVE CONT, MAY PRDCE NERVS SYS EFT, I.E.;
ATAXIA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: IMMED FLUSH W/LGE AMTS OF WATER FOR A MINIMUM OF 15 MIN,
LIFTING UPPER/LOWER LIDS. GET PROMPT MED ATTN. SKIN: FLUSH EXPOSED
AREAS THORO W/SOAP & WATER UNTIL ALL CHEM IS REMOVED. REMOVE CONTAM
CLT HG/LAUNDER BEFORE REUSE. INHAL: NOT NORMALLY REQD. REMOVE TO
FRESH AIR. IF BRTHG IS DFCLT, GIVE O2. IF BRTHG HAS STOPPED, GIVE
ARTF RESP. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF (SUPP
DATA)

Flash Point Method:SCC
Flash Point:230F,110C
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP . COOL EXPOSED EQUIPMENT W/WATER SPRAY.
Unusual Fire/Explosion Hazard:POLYMERIZATION MAY TAKE PLACE AT ELEVATED
TEMPERATURES.

Spill Release Procedures:WEAR PROT CLTHG. STOP LEAK IF YOU CAN DO IT
W/O RISK. FOR SML SPILLS, TAKE UP W/SAND OR OTHER INERT ABSORB MATL
& PLACE IN A CONTR FOR LATER DISPOSAL. IN BULK QTYS, PROD ABSORBED
ON INERT MATL MAY POL YMERIZE GENERATING SIGNIFICANT (ING 5)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE AT ROOM TEMP. AVOID EXCESSIVE
HEAT. STORE OUT OF DIRECT SUNLIGHT IN A DRY AREA. MAXIMUM STORAGE
TEMP IS 100F.
Other Precautions:THIS PROD CONTAINS TOXIC CHEM(S) FOR ROUTINE ANNUAL
TOXIC CHEM RELEASE REPORTING UNDER SEC 313: CUMENE
HYDROPEROXIDE-CAS#80-15- 9; SACCHARIN-CAS#81-07-2.

Respiratory Protection:NONE REQUIRED UNDER NORMAL HANDLING CNDTNS. USE
NIOSH/MSHA APPROVED RESPIRATOR IF VAPOR OR MIST LEVELS ARE
IRRITATING.
Ventilation:GENERAL VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE.
WASH HANDS W/SOAP & WATER IF CONT W/PROD OCCURS OR BEFORE EATING,
(ING 7)
Supplemental Safety and Health
BP: POLYMERIZES BEFORE BP ATTAINED. CNDTNS (POLYM): SURFACE CONDITIONER
IN LARGE QTYS, WILL ALSO CAUSE POLYMERIZATION. FIRST AID PROC:
CONSCIOUS, GIVE MILK OR WATER TO DILUTE STOMACH CONTENTS. KEEP WA
RM/QUIET. GET PROMPT MED ATTN. DO NOT ATTEMPT TO GIVE ANYTHING BY
MOUTH TO AN UNCON PERSON.

HCC:N1
Boiling Pt:B.P. Text:SUPDAT
Vapor Pres:0.01 @ 77F
Vapor Density:1.01
Spec Gravity:1.070
Solubility in Water:INSOLUBLE
Appearance and Odor:PURPLE LIQUID; MILD PLEASANT ODOR.
Percent Volatiles by Volume:<1

Stability Indicator/Materials to Avoid:YES
METALS AND THEIR SALTS, PERMA-LOK (R) ANAEROBIC SURFACE CONDITIONERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION COULD PRODUCE
CO, CO2, AND UNIDENTIFIED ORGANIC COMPOUNDS.
Conditions to Avoid Polymerization:PRODS ARE ANAEROBIC & POLYMERIZE IN
THE ABSENCE OF AIR. SUNLIGHT, EXCESSIVE HEAT, & CONTAM BY
METALS/ANAEROBIC (SUPDAT)

Waste Disposal Methods:WASTE DISPOSAL SHOULD BE I/A/W EXISTING FEDERAL,
STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.

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